Product ID:VR-3 VINYL RESIN-GREY 112-012
MSDS Date:06/27/1988
FSC:8010
NIIN:00N020403
MSDS Number: BLLKB

D J SIMPSON COMPANY

111 SOUTH MAPLE AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 415-873-5990

Info Phone: 415-873-5990

Cage: HO887

SIMPSON D J CO INC

2265 SOUTH SAN FRANCISCO, CA 94080-6303 US

Telephone: 415-873-5990

Cage: 33244

RUTILE; (TITANIUM DIOXIDE).

CAS: 1317-80-2

RTECS: VM2940000

Fraction By Weight: 10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 5 - 10%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 30 - 48%

OSHA PEL 200 PPM/300 STEL

ACGIH TLV: 200 PPM/300STEL 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 30%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

MAY EXPLODE DUE TO RESIDUES. OBSERVE MSDS. ALL

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:ANESTHETIC. IRRIT OF RESP TRACT
W/ HDCH, NAUS/DIZZ/UNCON/COMA. NOTE TO PHYS:INGEST OF
PROD/SUBSEQUENT VOMIT CAN RSLT IN ASPIR OF LIGHT HYDROCARBON LIQ
INTO LUNGS WHICH CAN CAUSE FATAL CHEM PNEUM ONIT. RPTD/PRLNG OCCUP
OVEREXP TO SOLV IN PROD MAY LEAD TO PERM BRAIN/NERV SYS DAM(ALSO
KNOWN AS (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:PAINTER'S/SOLV SYNDROME). INHAL:
DIZZ/NAUS/HDCH/IRRIT OF RESP TRACT, UNCON & EVEN ASPHY @ HIGH CONC.
IT HAS BEEN FOUND THAT TOLUENE CNTN COMPONENT WHICH CAN CAUSE
IRREVERSIBLE CHANGES IN DNA OF CELL. SKIN: IRRIT/DRY/CRACK.
EYES:IRRIT/EYE BURN. SKIN ABSORPTION:SEV IRRIT/BURN SENSATION.
CRACK/DEFAT/DERM (SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING HEART, LUNG, KIDNEY,
LIVER, SKIN DISORDERS.

First Aid:INHAL:REMOVE FROM EXPOSURE, RESTORE BRTHG. ADMINISTER O2 IF
NEEDED. SEEK MED HELP IMMED. EYE:FLUSH WITH LARGE AMOUNTS OF WATER
FOR AT LEAST 15 MIN WITH LIDS OPEN. SEE PHYS IMMED. SKIN:WASH WITH
SOAP A ND WATER. REMOVE CONTAMINATED CLOTHING.INGEST:DO NOT INDUCE
VOMIT. DRINK 1 OR 2 GLASSES OF WATER TO DILUTE. SEEK MED HELP
IMMED. KEEP PATIENT QUIET, WARM AND COMFORTABLE.

Flash Point Method:TCC
Flash Point:16.0F,-8.9C
Lower Limits:1.2%
Upper Limits:7.0%
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
FIGHT AS VOL LIQ FIRE. USE H2O TO COOL FIRE EXPOS CONTR. AVOID
SPREADING FIRE W/COOLING H2O, FOG (SUPP DATA)
Unusual Fire/Explosion Hazard:CLSD CONTR MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT. VAP MAY TRAVEL TO SOURCES OF IGNIT & CAUSE FLASH
FIRE. ISOLATE FROM ALL SOURCES OF HEAT. EMPTY CONTR(ING 5)

Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF
IGNITION. CONTAIN AND REMOVE WITH INERT ABSORBANT AND NON-SPARKING
TOOLS. WEAR PROTECTIVE EQUIPMENT DURING CLEANUP. CONTAIN LIQUID TO
PREVENT CONTAMINATION OF SOI L AND GROUND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CLOSURE TIGHT & CONTR IN UPRIGHT
POSITION. STORE AWAY FROM HEAT/OTHER SOURCES OF IGNIT. CONTR MUST
BE GROUND/BOND DURING LIQ TRANSFER.(SUPDAT)
Other Precautions:AVOID PRLNG BRTHG OF VAP, SKIN/EYE CONT. THIS
MATERIAL CONTAINS LESS THAN 1% BY WEIGHT OF PHOSPHORIC ACID AND
CARBON BLACK AND LESS THAN 0.1% BY WEIGHT OF VINYL CHLORIDE.

Respiratory Protection:USE NIOSH/MSHA APPROVED CHEMICAL MECHANICAL
FILTER RESPIRATOR.
Ventilation:REQUIRED, 200 CFM MINIMUM.
Protective Gloves:CHEMICALLY RESISTANT PLASTIC/RUB GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND SAFETY SHOWER IN WORK AREA
RECOMMENDED, USE PROTECTIVE HAND CREAM TO PREVENT DEFATTING OF SKIN
UPON EXPOS.
Work Hygienic Practices:WASH WITH SOAP AND WATER, REMOVE CONTAMINATED
CLOTHING BEFORE HANDLING FOOD OR SMOKING. DAILY SHOWERS
RECOMMENDED.
Supplemental Safety and Health
FIRE FIGHT:NOZZLES FOR H2O RECOM. EFTS OF OVEREXP:DERM MAY OCCUR ON
PRLNG EXPOS. INGEST:DIZZ/NAUS. NOT EXPECTED TO HAVE ACUTE SYSTEMIC
TOX BY INGEST. HNDLG/STOR PREC:HNDL WHERE VENT IS ADEQ/ AWAY FROM
SOURCES OF IGNIT. EMPTIED CONTR MAY STILL CNTN HAZ MATL HENCE IS
ADVISED TO OBSERVE MSDS WHEN HNDLG THEM.

HCC:F3
Boiling Pt:B.P. Text:174F,79C
Vapor Pres:SEE INGRED
Vapor Density:>AIR
Spec Gravity:1.0
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:VISCOUS LIQUID WITH DISTINCT SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS, ACIDS AND BASES.
Stability Condition to Avoid:AVOID PROLONGED BREATHING OF VAPORS, STORE
AWAY FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:USUAL PRODUCTS OF COMBUSTION; CARBON
MONOXIDE, CARBON DIOXIDE, OTHER OXIDES, SMOKE, FUMES, ETC.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.